Ionic liquid-promoted [3+2]-cycloaddition reactions of nitroformonitrile oxide generated by the cycloreversion of dinitrofuroxan

Add time:09/24/2019    Source:sciencedirect.com

A new approach to the synthesis of 3-nitroisoxazoles and 3-nitroisoxazolines based on the [3+2]-cycloaddition of nitroformonitrile oxide (NFNO), generated by the cycloreversion of dinitrofuroxan (DNFO), to acetylene and ethylene derivatives, under ionic liquid catalysis is developed. The approach is of a general nature and applicable to cycloaddition reactions with other dipolarophiles.

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