Highly efficient hydrogen generation from formic acid-Sodium formate (cas 141-53-7) over monodisperse AgPd nanoparticles at room temperature

Add time:09/29/2019    Source:infona.pl

Monodisperse AgPd alloy nanoparticles are synthesized by co-reduction of silver nitrate and palladium acetylacetonate in 1-octadecene and oleic acid using tert-butylamine borane as the reducing agent at 60°C. Thanks to the narrow size distribution of the AgPd alloy NPs and the synergistic effect with graphene, the as-synthesized Ag74Pd26/graphene exerts nearly 100% hydrogen selectivity and exceedingly high catalytic activity toward hydrogen generation from formic acid at room temperature, with the turnover frequency value of 572h−1.

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