Vibrational frequencies of partially deuterated hydrazinium (2+) sulfate

Add time:07/22/2019    Source:sciencedirect.com

The normal mode frequencies of the isotopically-substituted hydrazinium (2+) species N2DXH6−X (X = 1, 2…6) have been calculated using ab initio methods. The normal mode frequency shifts exhibit a wide range of dependence on the level of isotopic substitution and the nature of the normal mode. These data have been used to analyze the hydrazinium ion normal mode frequency patterns experimentally observed in a Raman and infrared spectroscopic study of hydrazinium sulfate, N2H6SO4, at different levels of deuterium substitution. These data indicate that there are no preferred sites for deuterium substitution in the cation.

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