Chemistry of organosilicon compounds
-
Add time:07/20/2019 Source:sciencedirect.com
Static conformations and the dynamic behavior of the radicals (MCH2)2ĊX (where M = SiR3, GeR3, or SnR3); X = H, CH3, or OSiMe3) have been investigated by ESR. At the preferred conformation, the two metal groups almost eclipse the singly-occupied carbon p-orbital and are located on the opposite sides of the CH2CXCH2 plane. The barriers for the flip-flop motion, evaluated by the line-shape analysis of the temperature-dependent ESR spectra, are closely related to those for the metal-group rotation about the C(α)C(β) bond.
We also recommend Trading Suppliers and Manufacturers of BIS(TRIMETHYLSILYLMETHYL)MERCURY (cas 13294-23-0). Pls Click Website Link as below: cas 13294-23-0 suppliers
Prev:Carbon-13 and proton NMR parameters of neopentyl-and trimethylsilylmethyl-thallium(III) derivatives and the x-ray crystal structure of bis(trimethylsilylmethyl)chlorothallium(III)
Next:Halomethyl-metal compounds) - 【Back】【Close 】【Print】【Add to favorite 】
- Related Information
- Pyridine functionalized alkyls of transition metals. Synthesis of bis[C,N-2-pyridylbis(trimethylsilyl)methyl]nickel07/24/2019
- Silicon migration and ring cleavage reactions of 2-alkyl-2-trimethylsilylmethyl-1,3-dithianes07/23/2019
- Halomethyl-metal compounds07/22/2019
- Carbon-13 and proton NMR parameters of neopentyl-and trimethylsilylmethyl-thallium(III) derivatives and the x-ray crystal structure of bis(trimethylsilylmethyl)chlorothallium(III)07/21/2019
- Bis[tris(trimethylsilylmethyl)stannyl]mercurya stable stannylmercury compound07/19/2019
- Tris(trimethylsilylmethyl)aluminium07/18/2019
- Trimethylsilylmethyl and bis(trimethylsilyl)methyl derivatives of boron, aluminium, cadmium and mercury07/17/2019
