Halomethyl-metal compounds
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Add time:07/22/2019 Source:sciencedirect.com
Phenyl(1,1-dichloroethyl)mercury has been prepared via 1,1-dichloroethyllithium and evaluated as a potential CH3CCl transfer agent. Although this mercurial reacted with triethylsilane to give Et3SiCHClCH3 (35%) and with allyltrimethylsilane to give 1-chloro-1-methyl-2-(trimethylsilylmethyl)cyclopropane (31%), its principal mode of reaction involved elimination of hydrogen chloride. The products resulting from this elimination were benzene (from HCl cleavage of PhHg bonds) and redistributed mercury compounds containing the concomitantly formed HgCClCH2 moiety. Possible reasons for this unexpected reaction are discussed.
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