Silicon migration and ring cleavage reactions of 2-alkyl-2-trimethylsilylmethyl-1,3-dithianes
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Add time:07/23/2019 Source:sciencedirect.com
The synthesis and ring cleavage reactions of 2-alkyl-2-trimethylsilylmethyl-1.3-dithianes are described. The cleavage lead to 2-alkylthio-1-vinylsilanes and, via silicon migration, to 2-[3-alkylthio-3-(trimethylsilyl)propylthio]-1-alkenes.
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