CAS No.57-50-1,Sucrose Suppliers,MSDS download

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Basic Information

Molecular Structure:
CAS No.:	57-50-1
Name:	Sucrose
Article Data:	114

Formula:	C₁₂H₂₂O₁₁
Molecular Weight:	342.3
Synonyms:	Sucrose(8CI);(+)-Sucrose;Amerfond;Beet sugar;Cane sugar;Carrare C 10;Confectioner's sugar;Frost Sugar;GNE 410;Granulated sugar;Khandsari;Manalox AS;Microse;NSC 406942;Rockcandy;Saccharose;Saccharum;Sucrose NF;Sugar;White sugar;a-D-Glucosyl-b-D-fructofuranoside;b-D-Fructofuranosyl a-D-glucopyranoside;
EINECS:	200-334-9
Density:	1.77 g/cm³
Melting Point:	185-187 °C(lit.)
Boiling Point:	697.1 °C at 760 mmHg
Flash Point:	375.4 °C
Solubility:	1970 g/L (15 ºC)
Appearance:	White crystalline powder
Hazard Symbols:	Xi
Risk Codes:	36/37/38
Safety:	24/25-37/39-26
PSA:	189.53000
LogP:	-5.39560

Synthetic route

: 302905-28-8
2,3,3',4,6-penta-O-benzylsucrose

: 57-50-1
Sucrose

Conditions

Conditions	Yield
With Amberlite IR-45(OH-); hydrogen; palladium on activated charcoal In methanol; ethyl acetate under 5688.78 Torr;	100%

: 126-14-7
sucrose octaacetate

: 57-50-1
Sucrose

Conditions

Conditions	Yield
magnesium oxide In methanol for 1h; Ambient temperature;	90%
With sodium methylate In methanol at 20℃; for 3h; Inert atmosphere;	90%
With methanol; potassium cyanide for 0.5h; Ambient temperature;	75%

inulin: inulin

A: 57-48-7
D-Fructose

B: 57-50-1
Sucrose

Conditions

Conditions	Yield
With niobic acid In water at 89.84℃; for 2h; Catalytic behavior; Reagent/catalyst; Autoclave; Inert atmosphere;	A 87% B n/a

: 53081-30-4
tetra-O-benzyl-α-D-galactosyl bromide

A (2S,3S,4R)-3,4-di-O-benzyl-N-hexacosanoyl-1-O-(2,3,4,6-tetra-O-benzyl-α-D-galactopyranosyl)-2-amino-1,3,4-octadecanetriol: (2S,3S,4R)-3,4-di-O-benzyl-N-hexacosanoyl-1-O-(2,3,4,6-tetra-O-benzyl-α-D-galactopyranosyl)-2-amino-1,3,4-octadecanetriol

B Sucrose: Sucrose

Conditions

Conditions	Yield
With tetrahexylammonium bromide In N,N-dimethyl-formamide; toluene for 72h; Ambient temperature;	A 74% B 8.2%

...Expand

inulin: inulin

A: 69-65-8
mannitol

B: 50-70-4
D-sorbitol

C: 57-50-1
Sucrose

Conditions

Conditions	Yield
With hydrogen In water at 89.84℃; under 15001.5 Torr; for 4h; Catalytic behavior; Reagent/catalyst; Pressure;	A 41% B 43% C 6%
With hydrogen In water at 89.84℃; under 15001.5 Torr; for 4h;	A 37% B 36% C 8.4%

...Expand

inulin: inulin

A: 470-23-5
D-fructose

B: 69-65-8
mannitol

C: 50-70-4
D-sorbitol

D: 57-50-1
Sucrose

Conditions

Conditions	Yield
With hydrogen In water at 89.84℃; under 15001.5 Torr; for 4h;	A 8.5% B 40% C 39% D 5.5%

...Expand

: 13360-52-6
Cellobiose

A: 50-99-7
D-glucose

B: 57-50-1
Sucrose

Conditions

Conditions	Yield
With sodium hydroxide In water at 130℃; for 6h; pH=8; pH-value; Inert atmosphere; Sealed tube;	A 11.8% B 10.1%

: 133-89-1
UDP-glucose

: 57-48-7
D-Fructose

: 57-50-1
Sucrose

Conditions

Conditions	Yield
mit Hilfe von Enzym-Praeparaten aus Weizenkeimen oder gruenen Erbsen;
Biosynthese mit Hilfe von Sucrosesynthase aus Weizenkeimen;
With sucrose synthase In aq. phosphate buffer at 37℃; for 1h; pH=8.5; Enzymatic reaction;

: 141-46-8
Glycolaldehyde

: 57-50-1
Sucrose

Conditions

Conditions	Yield
at 100℃; im Vakuum;

: 512-69-6
D-raffinose

: 57-50-1
Sucrose

Conditions

Conditions	Yield
With sodium periodate; ethanol; water anschl. mit wss. Na2CO3;

Raw Materials

69-79-4

57-48-7

6564-72-3

141-46-8

7732-18-5

7697-37-2

126-14-7

133-89-1

Downstream Products

921-62-0

50-99-7

106-45-6

67-64-1

513-86-0

97-67-6

24871-54-3

492-62-6

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Chemistry

Structure of D(+)-Sucrose (CAS NO.57-50-1):

Empirical Formula: C₁₂H₂₂O₁₁
Molecular Weight: 342.2965
Nominal Mass: 342 Da
Average Mass: 342.2965 Da
Monoisotopic Mass: 342.116212 Da
Index of Refraction: 1.656
Molar Refractivity: 70.85 cm³
Molar Volume: 192.8 cm³
Surface Tension: 113 dyne/cm
Density: 1.77 g/cm³
Flash Point: 375.4 °C
Enthalpy of Vaporization: 116.71 kJ/mol
Boiling Point: 697.1 °C at 760 mmHg
Vapour Pressure: 1.79E-22 mmHg at 25 °C
Melting point: 185-187 °C(lit.)
Storage tempreture: Store at RT.
Water solubility: 500 mg/mL
Appearance: White odorless crystalline or powdery solid
IUPAC Name: (2R,3R,4S,5S,6R)-2-[(2S,3S,4S,5R)-3,4-Dihydroxy-2,5-bis(hydroxymethyl)oxolan-2-yl]oxy-6-(hydroxymethyl)oxane-3,4,5-triol
Canonical SMILES: C(C1C(C(C(C(O1)OC2(C(C(C(O2)CO)O)O)CO)O)O)O)O
Isomeric SMILES: C([C@@H]1[C@H]([C@@H]([C@H]([C@H](O1)O[C@]2([C@H]([C@@H]([C@H](O2)CO)O)O)CO)O)O)O)O
InChI: InChI=1S/C12H22O11/c13-1-4-6(16)8(18)9(19)11(21-4)23-12(3-15)10(20)7(17)5(2-14)22-12/h4-11,13-20H,1-3H2/t4-,5-,6-,7-,8+,9-,10+,11-,12+/m1/s1
InChIKey: CZMRCDWAGMRECN-UGDNZRGBSA-N
Product Category of 4-Chloro-6,7-bis(2-methoxyethoxy)quinazoline (CAS NO.183322-18-1):
Oligosaccharide Compounds;Basic Sugars (Mono & Oligosaccharides);Biochemistry;Disaccharides;Sugars;Oligosaccharides

Uses

D(+)-Sucrose (CAS NO.57-50-1) can be widely used in food, cosmetics, and medicine, and is also used for the analysis of standard testing. It has been used as the standard for organic elemental analysis, too.

Toxicity Data With Reference

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
domestic animals - goat/sheep	LDLo	oral	40gm/kg (40000mg/kg)	BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) LUNGS, THORAX, OR RESPIRATION: RESPIRATORY STIMULATION GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA"	Nutrition Abstracts and Reviews. Vol. 30, Pg. 503, 1960.
mouse	LD50	intraperitoneal	14000mg/kg (14000mg/kg)		Pharmaceutical Chemistry Journal Vol. 15, Pg. 139, 1981.
rat	LD50	oral	29700mg/kg (29700mg/kg)	BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) LUNGS, THORAX, OR RESPIRATION: CYANOSIS GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA"	Toxicology and Applied Pharmacology. Vol. 7, Pg. 609, 1965.

Consensus Reports

Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program.

Safety Profile

Mildly toxic by ingestion. An experimental teratogen. Mutation data reported. Vigorous reaction with nitric acid or sulfuric acid (forms carbon monoxide and carbon dioxide). When heated to decomposition it emits acrid smoke and irritating fumes.
Hazard Codes: Irritant Xi
Risk Statements: 36/37/38
R36/37/38: Irritating to eyes, respiratory system and skin.
Safety Statements: 24/25-37/39-26
S24/25: Avoid contact with skin and eyes.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S37/39: Wear suitable gloves and eye/face protection.

Standards and Recommendations

OSHA PEL: TWA Total Dust: 15 mg/m³; Respirable Fraction: 5 mg/m³
ACGIH TLV: TWA (nuisance particulate) 10 mg/m³ of total dust (when toxic impurities are not present, e.g., quartz <1%); Not Classifiable as a Human Carcinogen
NIOSH REL: (Sucrose, Respirable Fraction) TWA 5 mg/m³; (Sucrose, total dust): TWA 10 mg/m³

Specification

D(+)-Sucrose , its cas register number is 57-50-1. It also can be called alpha-D-Glucopyranosyl beta-D-fructofuranoside ; beta-D-Fructofuranose-(2-1)-alpha-D-glucopyranoside ; Sucrose ; Saccharose ; and alpha-D-Glucopyranosyl beta-D-fructofuranoside . It is hazardous, so the first aid measures and others should be known. Such as: When on the skin: Should flush skin with plenty of water immediately for at least 15 minutes while removing contaminated clothing. Or in the eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. While, it's inhaled: Remove from exposure and move to fresh air immediately. Then you have the ingesting of the product: Wash mouth out with water. Notes to physician: Treat supportively and symptomatically.
In addition, D(+)-Sucrose (CAS NO.57-50-1) could be stable under normal temperatures and pressures. It is not compatible with strong oxidizing agents, and you must not take it with incompatible materials. And also prevent it to broken down into hazardous decomposition products: Carbon monoxide, carbon dioxide.