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1,2-Dichloro-1,2-difluoroethene

  • Name 1,2-Dichloro-1,2-difluoroethene
  • EINECS209-956-5
  • CAS No. 598-88-9
  • Density1.503 g/cm3
  • PSA0.00000
  • LogP2.52960
  • SolubilityN/A
  • Melting Point-130.5°C
  • FormulaC2Cl2F2
  • Boiling Point22.824 °C at 760 mmHg
  • Molecular Weight132.925
  • Flash Point-41.905 °C
  • Transport InformationN/A
  • AppearanceN/A
  • Safety9-23-36/37/39
  • Risk Codes23-36/37/38
  • Molecular Structure
    Molecular Structure of 598-88-9 (1,2-DICHLORO-1,2-DIFLUOROETHYLENE)
  • Hazard SymbolsIrritantXi
  • SynonymsIrritantXi
  • Article Data29

1,2-Dichloro-1,2-difluoroethene Synthetic route

54939-02-5

(2,2-dichloro trifluoro ethyl) trifluoro silane

A

79-35-6

1,1'-dichloro-2,2'-difluoroethene

B

598-88-9

1,2-dichloro-1,2-difluoroethene

C

7783-61-1

silicon tetrafluoride

Conditions
ConditionsYield
In neat (no solvent) pyrolysis at 140°C, 3 hours;;A 8%
B 90%
C 100%
In neat (no solvent) pyrolysis at 140°C, 3 hours;;A 8%
B 90%
C 100%
354-15-4

1,2,2-trichloro-1,2-difluoroethane

598-88-9

1,2-dichloro-1,2-difluoroethene

Conditions
ConditionsYield
With sodium hydroxide; tetra(n-butyl)ammonium hydroxide In water at 30℃; for 0.666667h; Product distribution / selectivity;98%
With sodium hydroxide; tetra(n-butyl)ammonium hydroxide In water at 30℃; for 0.666667h; Product distribution / selectivity;98%
With tetra(n-butyl)ammonium hydroxide; sodium hydroxide In water at 30℃;98%
76-12-0

CFC-112a

598-88-9

1,2-dichloro-1,2-difluoroethene

Conditions
ConditionsYield
zinc In isopropyl alcohol at 75 - 80℃; for 1h; Product distribution / selectivity;92%
With zinc In isopropyl alcohol at 75 - 80℃; for 1h; Product distribution / selectivity;92%
With zinc In isopropyl alcohol at 75 - 80℃; Inert atmosphere of nitrogen;92%
662-06-6

(2,2-dichloro trifluoro ethyl) trichloro silane

A

79-35-6

1,1'-dichloro-2,2'-difluoroethene

B

598-88-9

1,2-dichloro-1,2-difluoroethene

Conditions
ConditionsYield
In neat (no solvent) pyrolysis at 250°C;;A 7%
B 80%
In neat (no solvent) pyrolysis at 185°C;;A 7%
B 80%
In neat (no solvent) pyrolysis at 185°C;;A 7%
B 80%
In neat (no solvent) pyrolysis at 250°C;;A 7%
B 80%
at 250℃;
75-43-4

Dichlorofluoromethane

A

76-12-0

CFC-112a

B

598-88-9

1,2-dichloro-1,2-difluoroethene

Conditions
ConditionsYield
at 675℃;
76-12-0

CFC-112a

A

354-15-4

1,2,2-trichloro-1,2-difluoroethane

B

598-88-9

1,2-dichloro-1,2-difluoroethene

C

124-38-9

carbon dioxide

D

201230-82-2

carbon monoxide

Conditions
ConditionsYield
With ethanol; iron(III) chloride on activated carbon at 175℃; Product distribution; other chlorofluorocarbon; var. temp.; conversion vs. time of contact;
79-38-9

Chlorotrifluoroethylene

A

76-13-1

1,1,2-Trichloro-1,2,2-trifluoroethane

B

598-88-9

1,2-dichloro-1,2-difluoroethene

C

79-47-0

3-chloro-1,1,2,3,3-pentafluoro-propene

D

357-26-6

octafluoro-1-butene

E

115-25-3

Octafluorocyclobutane

F

356-18-3

1,2-dichloroperfluorocyclobutane

Conditions
ConditionsYield
at 450 - 710℃; for 0.000333333h; Product distribution; Mechanism; pyrolysis; variation of time and temp.; effect of contact time and temp.;A 5.2 % Chromat.
B 2.5 % Chromat.
C 27.0 % Chromat.
D 1.7 % Chromat.
E 1.6 % Chromat.
F 30.1 % Chromat.
79-38-9

Chlorotrifluoroethylene

A

116-14-3

polytetrafluoroethylene

B

1691-13-0

1,2-difluoroethene

C

359-04-6

1-chloro-1,2-difluoroethene

D

598-88-9

1,2-dichloro-1,2-difluoroethene

E

359-11-5

1,1,2-trifluoroethylene

Conditions
ConditionsYield
With monosilane under 0.7 Torr; Mechanism; Product distribution; Irradiation;
75-69-4

trichlorofluoromethane

67-64-1

acetone

A

421-71-6

1,1-dichloro-1-fluoro-2-methyl-propan-2-ol

B

598-88-9

1,2-dichloro-1,2-difluoroethene

Conditions
ConditionsYield
With magnesium In tetrahydrofuran at -20 - -15℃; Product distribution; other substrates, other products; also promoted by the Mg/LiCl-system;
354-15-4

1,2,2-trichloro-1,2-difluoroethane

alcoholic KOH-solution

alcoholic KOH-solution

598-88-9

1,2-dichloro-1,2-difluoroethene

1,2-Dichloro-1,2-difluoroethene Specification

The Ethene,1,2-dichloro-1,2-difluoro-, with the CAS registry number 598-88-9, is also known as 1,2-Dichlorodifluoroethylene. Its EINECS registry number is 209-956-5. This chemical's molecular formula is C2Cl2F2 and molecular weight is 132.92. What's more, both its IUPAC name and systematic name are the same which is called 1,2-Dichloro-1,2-difluoroethene.

Physical properties about Ethene,1,2-dichloro-1,2-difluoro- are: (1)ACD/LogP: 1.821; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 1.82; (4)ACD/LogD (pH 7.4): 1.82; (5)ACD/BCF (pH 5.5): 14.25; (6)ACD/BCF (pH 7.4): 14.25; (7)ACD/KOC (pH 5.5): 233.07; (8)ACD/KOC (pH 7.4): 233.07; (9)#H bond acceptors: 0; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 0; (12)Polar Surface Area: 0 Å2; (13)Index of Refraction: 1.393; (14)Molar Refractivity: 21.084 cm3; (15)Molar Volume: 88.431 cm3; (16)Polarizability: 8.358×10-24cm3; (17)Surface Tension: 20.083 dyne/cm; (18)Density: 1.503 g/cm3; (19)Flash Point: -41.905 °C; (20)Enthalpy of Vaporization: 25.813 kJ/mol; (21)Boiling Point: 22.824 °C at 760 mmHg; (22)Vapour Pressure: 821.052 mmHg at 25 °C.

When you are dealing with this chemical, you should be very careful. This chemical may cause inflammation to the skin or other mucous membranes and it is toxic by inhalation. It is irritating to eyes, respiratory system and skin. Therefore, you should wear suitable protective clothing, gloves and eye/face protection. You must keep container in a well-ventilated place and you can not breathe the gas/fumes/vapour/spray.

You can still convert the following datas into molecular structure:
(1) SMILES: ClC(F)=C(Cl)F
(2) InChI: InChI=1S/C2Cl2F2/c3-1(5)2(4)6
(3) InChIKey: UPVJEODAZWTJKZ-UHFFFAOYSA-N

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