14336-71-1

Chemical Properties
Safety information and MSDS
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Relevant articles and documents
Process route upstream and downstream products
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Home > CAS Database list > 14336-71-1

14336-71-1

Product Name:Calcium-45 chloride
CAS Number: 14336-71-1
EINECS:
Molecular Weight:110.984
Molecular Formula: CaCl₂
HS Code:
Mol File:14336-71-1.mol

Synonyms:Calciumchloride, labeled with calcium-45;Calcium chloride-45Ca;Calcium-45 chloride;Calcium-45 dichloride;

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Chemical Properties

Vapor Pressure: 33900mmHg at 25°C
PSA: 0.00000
LogP: -5.99200

Safety information and MSDS view more

Signal Word:no data available
Hazard Statement:no data available
First-aid measures: General adviceConsult a physician. Show this safety data sheet to the doctor in attendance.If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
Fire-fighting measures: Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus for firefighting if necessary.
Accidental release measures: Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8. Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Pick up and arrange disposal. Sweep up and shovel. Keep in suitable, closed containers for disposal.
Handling and storage: Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2. Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
Exposure controls/personal protection:Occupational Exposure limit valuesBiological limit values Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Eye/face protection Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Respiratory protection Wear dust mask when handling large quantities. Thermal hazards

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Relevant articles and documentsAll total 9 Articles be found

Electrochemical conversion of oxide spinels into high-entropy alloy

Sure, Jagadeesh,Sri Maha Vishnu,Schwandt, Carsten

, p. 133 - 141 (2019)

Single-phase equiatomic CoCrFeNi high-entropy alloy has been synthesised by direct electrochemical reduction from oxide precursors according to the concept of the FFC-Cambridge process. Metal oxide mixtures were heat treated in air to provide a blend of spinels, which was then employed as the cathode in the electro-deoxidation process. Melts of eutectic CaCl2-NaCl and pure CaCl2 were used as the electrolytes. Varying the experimental conditions in terms of processing temperature and time yielded CoCrFeNi alloys of diverse morphologies, ranging from fine dispersed powders to solid three-dimensional objects, as they are of relevance for additive manufacturing and near-net-shape fabrication. Notably, all solid alloy samples exhibited a higher hardness than calculated by the rule of mixture, despite the presence of significant residual porosity. The results highlight the versatility of the FFC-Cambridge process for alloy preparation and suggest the possibility of economically viable large-scale manufacture of steel-type high-entropy alloys.

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Venable, F. P.,Clarke, T.

, p. 306 - 310 (1895)

Richards, T. W.,Hoenigschmid, O.

, p. 28 - 35 (1911)

Attenuated total reflectance powder cell for infrared analysis of hygroscopic samples

Lekgoathi,Le Roux

, p. 529 - 531 (2011)

An attenuated total reflectance (ATR) sample cell has been designed, manufactured and subsequently used for the mid-infrared analysis of hygroscopic samples. This sample cell was installed as a simple drop-in replacement for the cell supplied with our commercially available Harrick Mvp-Pro FTIR-ATR accessory. Calcium chloride, a well-known desiccant that has a propensity to absorb water into its crystal lattice, was selected as non-infrared active substrate to accentuate the efficacy of the cell in preserving the anhydrous state of the sample by straightforward monitoring of the water bands. In contrast, mid-infrared spectra are presented that qualitatively demonstrate the rapid rate at which atmospheric moisture is incorporated into the anhydrous sample when analyzed using the conventional ATR cell assembly.

Richards, T. W.,Hoenigschmid, O.

, (1911)

The crystal chemistry of ca10-y(sio4) 3(so4)3cl2-x-2yfx ellestadite

Fang, Yanan,Ritter, Clemens,White, Tim

, p. 12641 - 12650 (2011)

Fluor-chlorellestadite solid solutions Ca10(SiO 4)3(SO4)3Cl2 -xFx, serving as prototype crystalline matrices for the fixation of hazardous fly ash, were synthesized and characterized by powder X-ray and neutron diffraction (PXRD and PND), transmission electron microscopy (TEM), and Fourier transform infrared spectroscopy (FTIR). The lattice parameters of the ellestadites vary linearly with composition and show the expected shrinkage of unit cell volume as fluorine (IR = 1.33 A) displaces chlorine (IR = 1.81 A). FTIR spectra indicate little or no OH- in the solid solutions. All compositions conform to P63/ m symmetry where F- is located at the 2a (0, 0, 1/4) position, while Cl- is displaced out of the 6h Ca(2) triangle plane and occupies 4e (0, 0, z) split positions with z ranging from 0.336(3) to 0.4315(3). Si/S randomly occupy the 6h tetrahedral site. Ellestadites rich in Cl (x ≤ 1.2) show an overall deficiency in halogens (a result of CaCl2 volatilization, with charge balance achieved by the creation of Ca vacancies (Ca2+ + 2Cl- →□Ca+ 2□lC) leading to the formula Ca10-y(SiO 4)3(SO4)3Cl2- x-2yFx. For F-rich compositions the vacancies are found at Ca(2), while for Cl-rich ellestadites, vacancies are at Ca(1). It is likely the loss of CaCl2 which leads tunnel anion vacancies promotes intertunnel positional disorder, preventing the formation of a P21/b monoclinic dimorph, analogous to that reported for Ca10(PO 4)6Cl2. Trends in structure with composition were analyzed using crystal-chemical parameters, whose systematic variations served to validate the quality of the Rietveld refinements.

ION SENSOR

-

, (2016/07/05)

Provided is a compound useful as a polyvalent metal ion sensor for calcium ions or the like which is capable of reversible sensing and of being integrated into a device, and an ion sensor using the compound. A copolymer comprising: a repeating unit (A) ha

Process route upstream and downstream products

Process route

: tricalcium diphosphate

: 201230-82-2
carbon monoxide

: 7782-50-5
chlorine

: 124-38-9,18923-20-1
carbon dioxide

: 14336-71-1
calcium chloride

: 10025-87-3,12599-09-6,63736-95-8,39380-77-3
trichlorophosphate

Conditions

Conditions	Yield
With pyrographite; In neat (no solvent); reaction of mixture of CO and Cl2 with Ca3(PO4)2 in presence of charcoal, reaction starts at 180°C and courses fast and quantitatively at 330 to 340°C;; POCl3 is nearly pure;;	>99

: tricalcium diphosphate

: 7782-50-5
chlorine

: 14336-71-1
calcium chloride

: 10025-87-3,12599-09-6,63736-95-8,39380-77-3
trichlorophosphate

Conditions

Conditions	Yield
In neat (no solvent);

: tricalcium diphosphate

: 7782-50-5
chlorine

: 124-38-9,18923-20-1
carbon dioxide

: 14336-71-1
calcium chloride

: 10025-87-3,12599-09-6,63736-95-8,39380-77-3
trichlorophosphate

Conditions

Conditions	Yield
With pyrographite; In neat (no solvent); reaction without heating (due to evolution of heat) in presence of charcoal at 700°C;;

: 7791-23-3
selenium oxychloride

: 7440-70-2
calcium

: 10025-68-0
diselenium dichloride

: 14336-71-1
calcium chloride

Conditions

Conditions	Yield

: 7647-01-0,15364-23-5
hydrogenchloride

: calcium sulfate

: 7782-50-5
chlorine

: 10025-67-9
disulfur dichloride

: 124-38-9,18923-20-1
carbon dioxide

: 201230-82-2
carbon monoxide

: 14336-71-1
calcium chloride

Conditions

Conditions	Yield
In neat (no solvent); at 700 - 800°C; acceleration in presence of NaCl or Na2SO4;;
In neat (no solvent);

: 22512-09-0
Ca⁽²⁺⁾*NbCl₇^(2-)=CaNbCl₇

: 10026-12-7
niobium pentachloride

: 14336-71-1
calcium chloride

Conditions

Conditions	Yield
In neat (no solvent); heating to 250°C at ambient pressure;;

: 7789-78-8
calcium hydride

: 10026-04-7,53609-55-5
tetrachlorosilane

: 10025-78-2
trichlorosilane

: 1333-74-0
hydrogen

: 14336-71-1
calcium chloride

: 7440-21-3
silicon

Conditions

Conditions	Yield
In neat (no solvent); reaction by leading an excess of SiCl4-vapour over heated CaH2-powder above red heat;; H2, HCl and few SiHCl3 als gasious products, CaCl2 and amorpheous Si as solid products;;

: 7789-78-8
calcium hydride

: 10026-04-7,53609-55-5
tetrachlorosilane

: 10025-78-2
trichlorosilane

: 1333-74-0
hydrogen

: 14336-71-1
calcium chloride

Conditions

Conditions	Yield
In neat (no solvent); byproducts: calcium silicide; reaction by leading SiCl4-vapour over an excess of heated CaH2-powder under red heat;; H2, HCl and few SiHCl3 als gasious products, CaCl2 and Ca-silicide as solid products;;