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Chlorotrimethylsilane

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Name

Chlorotrimethylsilane

EINECS 200-900-5
CAS No. 75-77-4 Density 0.868 g/cm3
PSA 0.00000 LogP 2.06010
Solubility reacts with water Melting Point -40 °C(lit.)
Formula C3H9ClSi Boiling Point 58.737 °C at 760 mmHg
Molecular Weight 108.643 Flash Point -18 °C
Transport Information UN 2924 3/PG 2 Appearance colourless liquid
Safety 26-36/37/39-45-16-36/37 Risk Codes 20/21-36/38-34-21-14-11-37-35-19-40-10
Molecular Structure Molecular Structure of 75-77-4 (Chlorotrimethylsilane) Hazard Symbols FlammableF,CorrosiveC
Synonyms

KA 31;KA 31 (silane);Monochlorotrimethylsilane;Monochlorotrimethylsilicon;NSC 15750;TMCS;TSL 8031;Trimethylchlorosilane;Trimethylsilicon chloride;Trimethylsilyl chloride;Trimethyl Chlorosilane;Trimethylchlorosilane(TMCS);Chlorotrimethylsilane;

Article Data 600

Chlorotrimethylsilane Synthetic route

75-76-3

tetramethylsilane

75-77-4

chloro-trimethyl-silane

Conditions
ConditionsYield
With 1,2-dichloro-ethane; aluminium trichloride at 130℃; for 17h;100%
With hydrogenchloride; aluminium trichloride
With chlorine; iodine In tetrachloromethane at 30℃;
With hydrogenchloride
686-69-1

diethylchlorophosphine

A

75-77-4

chloro-trimethyl-silane

B

131551-67-2

1-(1-tert-Butyl-2,2-diethyl-diphosphanyl)-2,2-dimethyl-propan-1-one

Conditions
ConditionsYield
at 100℃; for 1h;A n/a
B 100%
1719-57-9

Chloro(chloromethyl)dimethylsilane

1118-02-1

trimethylsilyl isocyanate

A

75-77-4

chloro-trimethyl-silane

B

86845-05-8

(chloromethyl)isocyanatodimethylsilane

Conditions
ConditionsYield
for 9h; Heating;A 100%
B 95%
7677-24-9

trimethylsilyl cyanide

63877-23-6

(trimethylsilyl)acetyl chloride

A

75-77-4

chloro-trimethyl-silane

B

54276-53-8

2-<(trimethylsilyl)oxy>propenenitrile

Conditions
ConditionsYield
A 100%
B 76%
814-49-3

diethyl chlorophosphate

18156-74-6

1-(Trimethylsilyl)imidazole

A

75-77-4

chloro-trimethyl-silane

B

16913-98-7

1-(Diethoxyphosphinyl)imidazole

Conditions
ConditionsYield
In dichloromethane for 1h; Ambient temperature;A n/a
B 100%
2524-04-1

diethyl phosphorochloridothioate

18156-74-6

1-(Trimethylsilyl)imidazole

A

75-77-4

chloro-trimethyl-silane

B

107313-21-3

Imidazol-1-yl-phosphonothioic acid O,O-diethyl ester

Conditions
ConditionsYield
In dichloromethane for 1h; Ambient temperature;A n/a
B 100%
2524-04-1

diethyl phosphorochloridothioate

18293-54-4

1-trimethylsilyl-1,2,4-triazole

A

75-77-4

chloro-trimethyl-silane

B

[1,2,4]Triazol-1-yl-phosphonothioic acid O,O-diethyl ester

Conditions
ConditionsYield
In dichloromethane for 1h; Ambient temperature;A n/a
B 100%
7677-24-9

trimethylsilyl cyanide

18162-48-6

tert-butyldimethylsilyl chloride

A

75-77-4

chloro-trimethyl-silane

B

56522-24-8

tert-butyldimethylsilyl cyanide

Conditions
ConditionsYield
With tetra-(n-butyl)ammonium iodide at 100 - 180℃; for 4h;A n/a
B 100%
A n/a
B 77%
124-63-0

methanesulfonyl chloride

18293-54-4

1-trimethylsilyl-1,2,4-triazole

A

75-77-4

chloro-trimethyl-silane

B

75668-13-2

1-Methanesulfonyl-1H-[1,2,4]triazole

Conditions
ConditionsYield
In dichloromethane for 1h; Ambient temperature;A n/a
B 100%
112-13-0

n-decanoyl chloride

17154-34-6

(trimethylsilyl)diphenylphosphine

A

75-77-4

chloro-trimethyl-silane

B

87361-17-9

(n-Decanoyl)diphenylphosphan

Conditions
ConditionsYield
In Petroleum ether for 0.5h;A n/a
B 100%

Chlorotrimethylsilane Chemical Properties

Molecular formula:C3H9SiCl
Molar mass:108.64 g/mol
Density:0.856 g/cm3, liquid
Melting point:-40 °C (233.2 K)
Boiling point:57 °C (330.2 K)
Solubility:in WATER reacts
Appearance:Colorless liquid, fumes in moist air
Chlorotrimethylsilane's Storage:Store in a cool, dry well-ventilated location, away from any area where the fire hazard may be acute. Outside or detached storage is preferred.
Stability: Reacts violently with WATER. Do not get WATER inside of container. Hydrochloric Acid is liberated on contact with moisture or heat.

Chlorotrimethylsilane Toxicity Data With Reference

Chlorotrimethylsilane's toxicity information:
Skin Contact:
Severe burns may occur from even a short time of contact. May be absorbed through the skin.
Eye Contact:
Eye contact produces severe burns, pain, swelling, corneal erosions and possibly blindness.
Inhalation:
Corrosive. Extremely destructive to tissues of the mucous membranes and upper respiratory tract. Symptoms may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea and vomiting. Inhalation may be fatal as a result of spasm inflammation and edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema.
Ingestion:
Corrosive. Swallowing can cause severe burns of the mouth, throat, and stomach, leading to death. Can cause sore throat, vomiting, diarrhea.

Chlorotrimethylsilane Safety Profile

Skin Contact:
In case of contact, immediately flush skin with plenty of WATER for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately.
Eye Contact:
Immediately flush eyes with plenty of WATER for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
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