Tetrahedron Letters p. 2559 - 2562 (1985)
Update date:2022-07-29
Topics:
Drexler, J.
Lindermayer, R.
Hassan, M. A.
Sauer, J.
Kinetic data (substituent effects, solvent effects, activation parameter) are reported for the reactions of trans-1-arylbutadienes 1 and 1,1-diarylbutadienes 3 with TCNE 4 and BTF 5. (2+2)- and (4+2)-cycloadducts 7 respectively 9 can rearrange or undergo cycloreversions with quite different reaction rates depending on the substituent in the aryl-ring.
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