New Entry to Pentamethylcyclopentadienyl Iron Chemistry and the Methylene Complexes 5-C5Me5)Fe(CO)(L)(CH2)>(+) (L = CO or PPh3)

DOI: 10.1039/c39850000835

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 835 - 837 (1985)

Update date:2022-08-04

Topics:

Authors:

Guerchais, Veronique

Astruc, Didier

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Article abstract of DOI:10.1039/c39850000835

Na<(η⁵-C5Me5)Fe(CO)2> (1), a precursor of (η⁵-C5Me5)Fe(CO)2(CH2OMe) (2), is conveniently obtained by Na-Hg reduction of <(η⁵-C5Me5)Fe(CO)2>2 overnight (20 deg C), complex (2) yielding <(η⁵-C5Me5)Fe(CO)2(CH2PPh3)

Full text of DOI:10.1039/c39850000835

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