BASE PROMOTED REARRANGEMENTS OF CYCLOPENTADIENYLACYL- AND -CARBOXYALKYL-METAL COMPLEXES

DOI: 10.1016/0022-328X(85)88045-1

Source and publish data:

Journal of Organometallic Chemistry p. C13 - C20 (1985)

Update date:2022-07-31

Topics:

Authors:

Abbott, Steven

Baird, Gordon J.

Davies, Stephen G.

Dordor-Hedgecock, Isabelle M.

Maberly, Timothy R.

et al. et al.

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Article abstract of DOI:10.1016/0022-328X(85)88045-1

Treatment of the complexes <(η⁵-C5H5)Fe(CO)(PPh3)COCH2R> and <(η⁵-C5H5)Fe(CO)(PPh3)CO2R> with n-butyllithium followed by methyl iodide gives the rearranged products <(η⁵-C5H4COCH2R)Fe(CO)(PPh3)Me> and <(η⁵-C5H4C

Full text of DOI:10.1016/0022-328X(85)88045-1

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Product name:(C₅H₄COCH₂CH₂CH₂CH₃)Fe(P(C₆H₅)3)(CO)(CH₃)

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