ENANTIOSELECTIVE SYNTHESIS OF A NOVEL TYPE OF OPTICALLY ACTIVE OCTAHEDRAL COMPLEXES, trans-. THE ESSENTIAL ROLE OF AXIAL LIGATION FOR Co-C ?-BOND FORMATION IN THE REACTION OF A Co(I) COMPLEX WITH OLEFINS

DOI: 10.1246/cl.1985.407

Source and publish data:

Chemistry Letters p. 407 - 410 (1985)

Update date:2022-08-04

Topics:

Authors:

Ohgo, Yoshiaki

Takeuchi, Seiji

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Article abstract of DOI:10.1246/cl.1985.407

C(+)₅₇₈- and A(-)₅₇₈-(XCH2CH2)(PPD)2(pyridine)Co have been synthesized by the enantioselective alkylation of I(PPD)2>^- with H2C=CHX in the presence of chiral amines, demonstrating the essential role of axial ligation for Co-C ?-bond formation.

Full text of DOI:10.1246/cl.1985.407

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