Journal of the Chemical Society, Dalton Transactions p. 2101 - 2112 (1985)
Update date:2022-07-29
Topics:
Mura, Pasquale
Olby, Bruce G.
Robinson, Stephen D.
Ruthenium and osmium precursors a range of pyridin-2-thiolate complexes including a carbonyl group a = 11.307(2), b = 11.083(3), c = 24.090(5) Angstroem, β = 109.47(2) deg, and Z = 4.The structure, which has been refined to R = 0.045 for 4375 observed reflections, consists of highly distorted octahedral ruthenium(II) molecules with monodentate (S-bonded) and bidentate (N,S-bonded) pyridine-2-thiolate ligands, a cis pair of carbonyl groups, and a triphenylphosphine ligand trans to the S-bonded pyridin-2-thiolate.Crystals of a = 10.317(3), b = 11.749(3), c = 12.517(3) Angstroem, α = 67.65(2), β = 70.55(2), γ = 86.43(2) deg, and Z = 2.The structure, which has been refined to R = 0.040 for 12196 observed reflections consists of highly distorted octahedral ruthenium(II) molecules with a cis pair of bidentate (N,S-bonded) pyridine-2-thiolate ligands (trans S atoms), a carbonyl group, and a triphenylphosphine ligand.
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(1985)
