METALLAHETEROCUMULENE III. UNGEWOEHNLICHE BILDUNG VON (CO)5Cr=C=NCPh2N=C=Cr(CO)5 BEI DER REAKTION VON + AlBr4- MIT TETRAHYDROFURAN

DOI: 10.1016/0022-328X(85)87303-4

Source and publish data:

Journal of Organometallic Chemistry p. C31 - C33 (1985)

Update date:2022-09-26

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Authors:

Seitz, Friedrich

Fischer, Helmut

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Article abstract of DOI:10.1016/0022-328X(85)87303-4

Pentacarbonyl(3,3-diphenyl-2-azaallenylidene)chromium tetrabromoaluminate, <(CO)5Cr=C=N=CPh2>⁺ AlBr4^-, reacts with THF in dichloromethane to give the dinuclear bis(isonitrile) complex <(CO)5Cr=C=N>2CPh2 which formally corresponds to the product of a reductive dimerization of two <(CO)5Cr=C=N=CPh2>⁺ moieties with concomitant elimination of one CPh2 fragment.

Full text of DOI:10.1016/0022-328X(85)87303-4

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