Total Synthesis of (+/-)-Velloziolone

DOI: 10.1021/jo00044a024

Source and publish data:

Journal of Organic Chemistry p. 4883 - 4888 (1992)

Update date:2022-07-30

Topics:

Authors:

Snider, Barry B.

Buckman, Brad O.

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Article abstract of DOI:10.1021/jo00044a024

The first total synthesis of the 9,10-seco-kaurene velloziolone (3) has been accomplished using an atom transfer tandem free-radical cyclization to prepare the 6-methylenebicyclo<3.2.1>octan-2-one moiety.The known diol 11 is converted to iodo acetate 10 i

Full text of DOI:10.1021/jo00044a024

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