The Low-Temperature, Ionic Diels-Alder Addition of Vinyl Ortho Esters to 1,3-Dienes

DOI: 10.1021/jo00245a058

Source and publish data:

Journal of Organic Chemistry p. 2392 - 2394 (1988)

Update date:2022-09-26

Topics:

Authors:

Gassman, Paul G.

Chavan, Subhash P.

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Article abstract of DOI:10.1021/jo00245a058

3,3,3-Triethoxypropene (triethyl orthoacrylate) was added to a series of 1,3-dienes in the presence of trimethylsilyl triflate at -78 to 0 deg C to produce 53-83percent yields of the adduct of ethyl acrylate and the 1,3-dienes.The products were formed und

Full text of DOI:10.1021/jo00245a058

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