Reaction of Cp*Ir(CO)2 with activated perfluoroaromatic compounds: Formation of metallocarboxylic acids via aromatic nucleophilic substitution

DOI: 10.1021/om701078q

Source and publish data:

Organometallics p. 1247 - 1253 (2008)

Update date:2022-08-04

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Authors:

Chan, Pek Ke

Leong, Weng Kee

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Article abstract of DOI:10.1021/om701078q

The reaction of Cp*Ir(CO)₂ with activated perfluoroaromatic compounds such as pentafluoropyridine and -benzonitrile afforded the metallocarboxylic acids Cp*Ir(COOH)(L)(CO), L = C ₅F₄N or C₆F₄CN, respe

Full text of DOI:10.1021/om701078q

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Product name:[(C₅Me₅)Ir(CO)(COO-i-Pr)(p-C₆F₄CN)]

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