Tetrahedron Letters p. 2283 - 2286 (1988)
Update date:2022-07-29
Topics:
Stork, Gilbert
Nakatani, Kazuhiko
It is possible to control the regiochemistry of the Rh-catalyzed insertion of α-diazoketones into C-H bonds by taking advantage of the greatly reduced rate of insertion into methylenes which are α or β to a carbonyl function.The 2-carboxyethyl group is especially useful for this purpose because it can be transformed eventually into a variety of other substituents.
View MoreContact:
Address:
Buffett (China) Holding Co.,Ltd
Contact:4006570891
Address:
TIANJIN ZHONGXIN CHEMTECH CO.,LTD.
Contact:86-022-89880739
Address:10B, Pan China International Center, No. 931 YingKou Road, TangGu, Tianjin, China, 300451
Shanghai Yuantai Chemical Products Co., Ltd
Contact:021--66129803
Address:Chengyin Road,Shanghai,China
jiangsu senxuan pharmaceutical and chemical co.,ltd
Contact:86-523-87982810
Address:hongqiao industrial zone,taixing,jiangsu china
Doi:10.1039/jr9500000978
(1950)Doi:10.1002/chem.200903450
(2010)Doi:10.1007/s10053-000-8805-1
(1958)Doi:10.1016/j.ejmech.2009.10.004
(2010)Doi:10.1016/0008-6215(85)85036-9
(1985)Doi:10.1016/S0040-4020(01)89488-6
(1989)