Tetrahedron Letters p. 2283 - 2286 (1988)
Update date:2022-07-29
Topics:
Stork, Gilbert
Nakatani, Kazuhiko
It is possible to control the regiochemistry of the Rh-catalyzed insertion of α-diazoketones into C-H bonds by taking advantage of the greatly reduced rate of insertion into methylenes which are α or β to a carbonyl function.The 2-carboxyethyl group is especially useful for this purpose because it can be transformed eventually into a variety of other substituents.
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