Tetrahedron Letters p. 3453 - 3456 (1985)
Update date:2022-08-04
Topics:
Fetizon, Marcel
Hanna, Issam
Rens, Janine
1,4-Dioxen-2-yl lithium 2 reacts with ketones or aldehydes to give alcohols 3 which lead after an allylic rearrangement under mild conditions, followed by reduction and hydrolysis to α-hydroxymethyl ketones in fair yields.
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