Tetrahedron Letters p. 5959 - 5962 (1995)
Update date:2022-07-31
Topics:
Pansare, Sunil V.
Ravi, R. Gnana
Substrate directed reduction of 'S'-2-hydroxymethylpyrrolidine derived α-keto amides with tetramethylammonium triacetoxyborohydride proceeds with good stereoselectivity at room temperature.A reversal of stereoselectivity is observed in reductions with conventional borohydride reducing agents in protic solvents.
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