Journal of the Chemical Society. Perkin transactions II p. 1961 - 1964 (1986)
Update date:2022-08-04
Topics:
Osek, Jerzy
Oszczapowicz, Janusz
Drzewinski, Witold
Rate of reaction of seven N,N-dialkylformamide acetals R2N-CH(OR2)2 with a series of anilines substituted on the phenyl ring have been measured in benzene, methanol, chloroform, and tetrahydrofuran by use of a g.l.c. method.In each case studied reaction is irreversible and obeys a second-order kinetic equation.Reaction rates correlate with Hammett ? constants for substituents on the phenyl ring of the aniline molecule.On the basis of the kinetic data, the mechanism of reaction is discussed.
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Doi:10.1021/ja00273a023
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