The Intramolecular Wadsworth-Emmons Condensation of γ-(Acyloxy)-β-ketophosphonates. A New Route to 3(2H)-Furanones

DOI: 10.1021/jo00363a023

Source and publish data:

Journal of Organic Chemistry p. 2525 - 2529 (1986)

Update date:2022-09-26

Topics: 3(2H)-Furanones

Authors:

Sampson, Paul

Roussis, Vassilios

Drtina, Gary J.

Koerwitz, Frederick L.

Wiemer, David F.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00363a023

A series of γ-(acyloxy)-β-ketophosphonates has been synthesized, either from the corresponding α-iodo keto ester by an Arbuzov reaction or by acylation of an alkylphosphonate anion.When treated with potassium carbonate in DMF, these γ-(acyloxy)-β-ketophos

Full text of DOI:10.1021/jo00363a023

Products guided by the article

Product name:Benzoic acid 3-(dimethoxy-phosphoryl)-1,1-dimethyl-2-oxo-propyl ester

Cas No:102307-34-6

R&D Labs maybe for 102307-34-6

SHANGHAI BIOSUNDRUG CO.,LTD.

Contact:86-21-34622192，13917187091，21-34622765

Address:No. 500 Caobao Road Shanghai P.R China
NINGBO PANGS CHEM INT’L CO., LTD.

Contact:+86-0574-27666801

Address:Floor 21, Building 11, Xintiandi, No. 689, Shijiroad, Ningbo, Zhejiang, China
Huangshi Shennong Chemical Technology Co., Ltd

Contact:+86-714-3072290

Address:Eastern industrial park , Tieshan district , Huangshi city ,Hubei province , China
Mashilabs(shanghai)Co.,ltd

Contact:+86-21-54391580

Address:Room 502,No.65,Lane 2388 Hongxin Road,Shanghai,China
Tianjin Emulsion Science&Technology Development Co.,Ltd

Contact:13901380442

Address:Vake Garden New Town New Yi Bai Road Beichen District Tianjin,China

Relevant to this article

The Chemistry of L-Ascorbic and D-Isoascorbic Acids. 2. R and S Glyceraldehydes from a Common Intermediate

Doi:10.1021/jo00261a004
(1988)
Confirmation of the stereostructure of (+)-cytostatin by fluorous mixture synthesis of four candidate stereoisomers

Doi:10.1002/anie.200704893
(2008)
Stereospecific synthesis of D-glycero-D-ido-oct-2-ulose

Doi:10.1007/s007060170088
(2001)
Electrooxidative formation of 1,2-diaroylcyclopropanes from 1,3-diaroylpropanes in the presence of KI

Doi:10.1246/bcsj.76.207
(2003)
Synthesis, antimalarial activity, and quantitative structure-activity relationships of tebuquine and a series of related 5-[(7-chloro-4-quinolinyl)amino]-3-[(alkylamino)methyl][1,1'-biphenyl]-2-o ls and N(ω)-oxides^1,2

Doi:10.1021/jm00156a009
(1986)
Synthesis and Antimitogenic Activities of Four Analogues of Cyclosporin A Modified in the 1-Position

Doi:10.1021/jm00156a014
(1986)

Article Doi