Influence of Hydrogen Ion Activity and General Acid-Base Catalysis on the Rate of Decomposition of Hydrogen Peroxide by a Novel Nonaggregating Water-Soluble Iron(III) Tetraphenylporphyrin Derivative

DOI: 10.1021/ja00275a033

Source and publish data:

Journal of the American Chemical Society p. 4433 - 4445 (1986)

Update date:2022-08-04

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Authors:

Zipplies, Matthias F.

Lee, William A.

Bruice, Thomas C.

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Article abstract of DOI:10.1021/ja00275a033

The synthesis and characterization of 5,10,15,20-tetrakis(2,6-dimethyl-3-sulfonatophenyl)porphyrin (3) and its iron(III) complex (3-Fe^III) are described.Both 3 and 3-Fe^III hydrate exist as a mixture of atropisomers due to the dissymm

Full text of DOI:10.1021/ja00275a033

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