Synthesis of chiral bicyclo [2.2.2] oct-5-en-2-ones via an intramolecular alkylation reaction

DOI: 10.1039/p19960001305

Source and publish data:

Journal of the Chemical Society. Perkin Transactions 2 (2001) p. 1305 - 1311 (1996)

Update date:2022-08-04

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Authors:

Srikrishna, Adusumilli

Veera Raghava Sharma

Danieldoss, Savariappan

Hemamalini, Parthasarathy

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Article abstract of DOI:10.1039/p19960001305

Generation of the thermodynamic dienolate of 9-bromocarvone derivatives 5,7 and 11 furnished the chiral bicyclo[2.2.2]octenones 6, 8 and 9 and 12 and 13 containing a bridgehead methyl group via an intramolecular alkylation reaction. In an analogous manner

Full text of DOI:10.1039/p19960001305

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