HIGHLY STEREOSELECTIVE REACTION OF α-METHYLTHIO ALDEHYDES WITH ALLYLTRIPHENYLSTANNANE : SYNTHESIS OF anti-β-METHYLTHIO ALCOHOLS.

DOI: 10.1016/S0040-4039(00)95061-5

Source and publish data:

Tetrahedron Letters p. 6235 - 6238 (1985)

Update date:2022-08-04

Topics:

Authors:

Shimagaki, Masayuki

Takubo, Hideki

Oishi, Takeshi

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Article abstract of DOI:10.1016/S0040-4039(00)95061-5

The reaction of α-methylthio aldehydes 4 <*> with allyltriphenylstannane 5 in the presence of SnCl4 gave anti-β-methylthio alcohols 6 in excellent selectivity.

Full text of DOI:10.1016/S0040-4039(00)95061-5

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