Cyclocarbonylation of 1,1,3-trisubstituted 1,3-Dienes via their Tricarbonyl Iron Complexes. Synthesis of cyclocondensed and (or) spirocyclic (optically active) Cyclopenten-2-ones

DOI: 10.1016/S0040-4039(00)60189-2

Source and publish data:

Tetrahedron Letters p. 7365 - 7368 (1992)

Update date:2022-08-03

Topics:

Authors:

Franck-Neumann, Michel

Vernier, Jean-Michel

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Article abstract of DOI:10.1016/S0040-4039(00)60189-2

Tricarbonyl iron complexes of 1,1,3 and 1,1,2,3-substituted 1,3-dienes are decomplexed under mild conditions by aluminium halides to conjugated cyclopentenones.This is illustrated for the cyclic substitution patterns A and C, leading to spirocyclic and cy

Full text of DOI:10.1016/S0040-4039(00)60189-2

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