Chemistry Letters p. 1925 - 1928 (1985)
Update date:2022-07-29
Topics:
Tadano, Kin-Ichi
Idogaki, Yoko
Yamada, Hirohiko
Suami, Tetsuo
The ortho ester Claisen rearrangement of D-ribo- or L-lyxo-hexofuranose derivative which possesses an allyl alcohol functionality on C-3, proceeds stereoselectively to give a 3-C-dialkylated product.The stereochemistry of a newly introduced quaternary center of the product was unambiguously established by a chemical modification.
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Doi:10.1002/anie.202000812
(2020)Doi:10.1021/ol8010979
(2008)Doi:10.1021/ja057954f
(2006)Doi:10.1007/s00044-008-9089-0
(2008)Doi:10.1246/cl.1985.1335
(1985)Doi:10.1021/jo00370a020
(1986)
