Organic Letters p. 3445 - 3448 (2008)
Update date:2022-08-03
Topics:
Lu, Yin-Suo
Li, Qin
Zhang, Li-He
Ye, Xin-Shan
(Chemical Equation Presented) A new efficient pre-activation method for the highly α-stereoselective glycosylation of 2-deoxysugars and 2,6-dideoxysugars has been developed using 2-deoxy- and 2,6- dideoxythioglycosides as glycosyl donors. The approach allows a wide range of glycosyl acceptors and donors to be used; the α-selectivity is very good to excellent.
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