Tetrahedron p. 3655 - 3661 (1985)
Update date:2022-08-03
Topics:
Wakabayashi, Yukio
Fukuda, Yukitoshi
Shiragami, Hiroshi
Utimoto, Kiitiro
Nozaki, Hitosi
A procedure is described for the synthesis of furans from 3-alkyn-1,2-diols or 2-methoxy-3-alkyn-1-ols by palladium catalyzed intramolecular addition of alcoholic moiety to acetylene linkage followed by elimination of water or methanol.The intermediary 3-furylpalladiums can be trapped with allyl halides affording 3-allylfurans in good yields.
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Doi:10.1002/anie.200800423
(2008)Doi:10.1021/acs.jmedchem.6b01254
(2017)Doi:10.1016/S0040-4020(01)91364-X
(1985)Doi:10.1023/A:1019749427770
(2002)Doi:10.1021/ja01483a013
(1961)Doi:10.1021/jo01347a013
(1966)
