PREPARATION OF A TETRAHYDROBORATE COMPLEX OF RHENIUM(I), cis-2-BH4)(Ph2PCH2PPh2)2>

DOI: 10.1016/S0022-328X(00)99715-8

Source and publish data:

Journal of Organometallic Chemistry p. C33 - C35 (1986)

Update date:2022-07-30

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Authors:

Pombeiro, Armando J. L.

Richards, Raymond L.

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Article abstract of DOI:10.1016/S0022-328X(00)99715-8

Dechlorination reactions of the dinitrogen and the isocyanide complexes trans- (I: L = N2; II: L = CNMe; dppe = Ph2PCH2CH2PPh2) by TlBF4, in the presence of NaBH4 afford cis-2-BH4)(dppe)2> (which has a static tetrahydroborate ligand) and the hydride complex trans-, respectively.

Full text of DOI:10.1016/S0022-328X(00)99715-8

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