THE SYNTHESIS OF CATIONIC A-FRAME ORGANOPLATINUM(II) DIMERS

DOI: 10.1016/S0022-328X(00)86655-3

Source and publish data:

Journal of Organometallic Chemistry p. 135 - 138 (1981)

Update date:2022-07-30

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Authors:

Anderson, G.K.

Clark, H.C.

Davies, J.A.

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Article abstract of DOI:10.1016/S0022-328X(00)86655-3

The complex (cod=1,5-cyclooctadiene) reacts with Ph2PCH2PPh2 (dppm) to yield the cationic A-frame organoplatinum(II) dimer, Cl.The phenyl and methyl analogues yield both mononuclear and the corresponding dimeric products.Previous work on the methylplatinum complex is not substantiated by these results.

Full text of DOI:10.1016/S0022-328X(00)86655-3

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Product name:Pt((C₆H₅)2PCH₂P(C₆H₅)2)Cl(C₆H₅)

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