THE ESTER ENOLATE CLAISEN REARRANGEMENT. SYNTHESIS OF A C(1)-C(6) ERYTHRONOLIDE FRAGMENT

DOI: 10.1016/S0040-4039(00)85502-1

Source and publish data:

Tetrahedron Letters p. 449 - 452 (1986)

Update date:2022-08-04

Topics:

Authors:

Burke, Steven D.

Schoenen, Frank J.

Murtiashaw, Charles W.

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Article abstract of DOI:10.1016/S0040-4039(00)85502-1

An enantioselective route to the C(1)-C(6) erythronolide unit 10 is described, involving the dioxanone-to-dihydropyran enolate Claisen rearrangement (7<*>8), regio- and stereoselective hydroboration to give 9a, and reductive fragmentation of the heterocyc

Full text of DOI:10.1016/S0040-4039(00)85502-1

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