Tetrahedron Letters p. 449 - 452 (1986)
Update date:2022-08-04
Topics:
Burke, Steven D.
Schoenen, Frank J.
Murtiashaw, Charles W.
An enantioselective route to the C(1)-C(6) erythronolide unit 10 is described, involving the dioxanone-to-dihydropyran enolate Claisen rearrangement (7<*>8), regio- and stereoselective hydroboration to give 9a, and reductive fragmentation of the heterocyc
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