Organic and Biomolecular Chemistry p. 2276 - 2281 (2008)
Update date:2022-08-04
Topics:
Nieto, Natalia
Munslow, Ian J.
Barr, Jonathan
Benet-Buchholz
Vidal-Ferran, Anton
A study, via isotopic labeling, of the stereoselective processes in a Shi-type epoxidation, has revealed that the chiral platform provided by the catalyst mediates the transfer of the pro-S "O" of the related dioxirane species to the alkene in a doubly stereoselective manner.
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