
Organometallics p. 3630 - 3632 (2008)
Update date:2022-08-02
Topics:
Galan, Brandon R.
Pitak, Mateusz
Keister, Jerome B.
Diver, Steven T.
Carbon monoxide or an aryl isocyanide promotes a benzylidene carbene transfer from ruthenium to tricyclohexy-lphosphine in the first-generation Grubbs carbene complex. The resulting ruthenium(II) complexes have been isolated and structurally characterized by X-ray crystal structure analysis; aprobable mechanism for the ligand-promoted transformation is also discussed.
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