Synthesis p. 956 - 958 (1985)
Update date:2022-08-03
Topics:
Baudin, J.-B.
Bekhazi, M.
Julia, S. A.
Ruel, O.
Jong, R. L. P. de
Brandsma, L.
Reaction of bromomagnesium benzenamides with 1-alkynyl thiocyanates affords the title sulphenamides.On heating in benzene, these sulphenamides undergo <3.3>-sigmatropic rearrangements followed by cyclisation of the intermediate thioketenes yielding indoli
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