Deciphering DNA-based asymmetric catalysis through intramolecular Friedel-Crafts alkylations

DOI: 10.1039/c2cc35625b

Source and publish data:

Chemical Communications p. 10398 - 10400,3 (2012)

Update date:2022-08-05

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Authors:

Park, Soyoung

Ikehata, Keiichi

Watabe, Ryo

Hidaka, Yuta

Rajendran, Arivazhagan

Sugiyama, Hiroshi

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Article abstract of DOI:10.1039/c2cc35625b

We describe asymmetric intramolecular Friedel-Crafts alkylations with a DNA-based hybrid catalyst and propose a plausible binding model. This study shows promise for studying relationships between the helical chirality of DNA and enantioselectivity of the chemical reaction.

Full text of DOI:10.1039/c2cc35625b

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