Carbonylation of Methanol at Unusually Low Temperature and Pressure with cis-RhCl(CO)2Ph2P(CH2)2P(O)Ph2

DOI: 10.1039/c39870001891

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1891 - 1892 (1987)

Update date:2022-09-26

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Authors:

Wegman, Richard W.

Abatjoglou, Anthony G.

Harrison, Arnold M.

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Article abstract of DOI:10.1039/c39870001891

cis-RhCl(CO)2Ph2P(CH2)2P(O)Ph2, the only species observed during catalysis, formed from and CO, is the sole active species observed during catalytic studies and results in the carbonylation of methanol with catalyst turnover frequencies approach

Full text of DOI:10.1039/c39870001891

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Product name:RhCl(CO)2(C₆H₅)2PCH₂P(O)(C₆H₅)2

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