Tetrahedron Letters p. 4949 - 4952 (1982)
Update date:2022-08-03
Topics:
Barton, Derek H.R.
Lusinchi, Xavier
Milliet, Pierre
Phenylseleninic anhydride reacts rapidly with indolines at 0 deg C to give, when the β-position is substituted, the corresponding indoles.When the β-position is unsubstituted β-phenylselenoindoles are formed.These are readily reduced by nickel boride to the parent indole.Tetrahydroisoquinoline is dehydrogenated with comparable ease.Phenylseleninic acid is also an efficient agent for these dehydrogenations.
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