CARBONYL COMPLEXES OF MANGANESE(I) WITH CHELATING PHOSPHINO-ALKYL OR -ACYL LIGANDS. CRYSTAL AND MOLECULAR STRUCTURE OF (CO)2(dppm)>

DOI: 10.1016/0022-328X(85)80418-6

Source and publish data:

Journal of Organometallic Chemistry p. 193 - 204 (1985)

Update date:2022-07-30

Topics:

Authors:

Carriedo, G. A.

Soto, J. B. Parra

Riera, V.

Solans, X.

Miravitlles, C.

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Article abstract of DOI:10.1016/0022-328X(85)80418-6

The phosphine Ph2PCH2CH2Cl reacts with fac- (X = Cl or Br) in refluxing toluene to give the complexes cis,cis- (I).Treatment of those species with Na amalgam in THF leads to the alkyl complex (CO)

Full text of DOI:10.1016/0022-328X(85)80418-6

Products guided by the article

Product name:Mn(CO)3((C₆H₅)2PCH₂P(C₆H₅)2)((C₆H₅)2PCH₂CH₂Cl)⁽¹⁺⁾*ClO₄^(1-)=[Mn(CO)3((C₆H₅)2PCH₂P(C₆H₅)2)((C₆H₅)2PCH₂CH₂Cl)]ClO₄

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