Convenient Synthesis of Alkyl (Z)- and (E)-2,3-Bis(trimethylstannyl)alk-2-enoates and N,N-Dimethyl (E)-2,3-Bis(trimethylstannyl)alk-2-enamides

DOI: 10.1039/c39860000626

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 626 - 627 (1986)

Update date:2022-08-05

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Authors:

Piers, Edward

Skerlj, Renato T.

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Article abstract of DOI:10.1039/c39860000626

Palladium(0)-catalysed addition of (Me3Sn)2 to the α,β-acetylenic esters (1a-n) and amides (4a-d) provides the (Z)-2,3-bis)trimethylstannyl)alk-2-enoates (2a-n) and the (E)-2,3-bis(trimethylstannyl)alk-2-enamides (6a-d), respectively; thermolysis of (2a-h

Full text of DOI:10.1039/c39860000626

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