Chemical and Pharmaceutical Bulletin p. 1435 - 1440 (1995)
Update date:2022-07-29
Topics:
Ozaki
Mitoh
Ohmori
Substituted (methylene)cyclopentanes were prepared by one-step reaction at room temperature from butynyl iodides and activated olefins by sequencing of free radical addition and cyclization reactions. The reactions, which were conducted by indirect electroreduction catalyzed by a nickel(II) complex, proceeded with modest selectivity for formation of the Z(methylene)cyclopentanes.
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