Gold(I)-catalyzed intermolecular addition of carbon nucleophiles to 1,5- and 1,6-enynes

DOI: 10.1021/jo8014769

Source and publish data:

Journal of Organic Chemistry p. 7721 - 7730 (2008)

Update date:2022-08-04

Topics:

Authors:

Amijs, Catelijne H. M.

Lopez-Carrillo, Veronica

Raducan, Mihai

Perez-Galan, Patricia

Ferrer, Catalina

Echavarren, Antonio M.

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Article abstract of DOI:10.1021/jo8014769

(Chemical Equation Presented) Gold(I)-catalyzed addition of carbon nucleophiles to 1,6-enynes gives two different type of products by reaction at the cyclopropane or at the carbene carbons of the intermediate cyclopropyl gold carbenes. The 5-exo-dig cycli

Full text of DOI:10.1021/jo8014769

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