Journal of Organometallic Chemistry p. 105 - 110 (1986)
Update date:2022-08-05
Topics:
Harris, Ronald L.
The ortho, meta and para complexes of bis(η6-chlorobenzotrifluoride)chromium(0) were made by metal-vapor synthesis.Nucleophilic substitutions by thiophenoxide of these complexes are compared to nucleophilic substitutions by thiophenoxide on the uncoordinated arenes.It was found that substitution at the chloro position is more facile on the complexes than on the free arenes.Substitution of the chloro on the meta-isomer sandwich was more facile than substitution of the chloro on the ortho-isomer sandwich, contrary to the observed reactivity pattern in the free arenes.
View MoreContact:+86 512 6287 2180
Address:398 Ruoshui Road, Suzhou Industrial Park, Suzhou, Jiangsu, P. R. China
Contact:86-516-66656369
Address:The west road of Huaihai, Xuzhou, China
Shanghai Yuking Water Soluble Material Tech Co., Ltd
Contact:86-21-68286299
Address:4F, 13B, No. 600, South Xinyuan Road 201306, Shanghai, China
SICHUAN TONGSHENG AMINOACID CO.LTD
website:http://www.aminoacid.cc
Contact:86-838-2274206/2850606
Address:Room 1-11-1,No.19 of North TianShan Road,Deyang,Sichuan China
website:http://www.simagchem.com
Contact:+86-592-2680277
Address:21/F Hualong Office Building,No.6 Hubin East Road, Xiamen,China
Doi:10.1074/jbc.M111.252726
(2011)Doi:10.1021/jo801294p
(2008)Doi:10.1021/acs.orglett.9b04414
(2020)Doi:10.1021/jp803577d
(2008)Doi:10.1016/j.tetlet.2008.06.091
(2008)Doi:10.1248/cpb.42.963
(1994)
