Highly stereoselective synthesis of 2'-deoxy-α-ribonucleosides and 2-deoxy-α-C-ribofuranosides by remote stereocontrolled glycosylation

Article abstract of DOI:10.1246/cl.1997.389

A new and efficient method for catalytic highly α-selective N-and C-glycosylations of 2-deoxyribose derivative with various trimethylsilylated nucleophiles was successfully developed by utilizing effective remote stereocontrol with 5-O-diethylthio carbamo