Welcome to LookChem.com Sign In|Join Free

Article Doi

The Preparation and Crystal and Molecular Structures of Trichlorobis(methyldiphenylphosphine)vanadium(III) and its Acetonitrile Adduct

DOI: 10.1039/DT9860002253

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2253 - 2258 (1986)

Update date:2022-08-03

Topics:

Authors:

Bultitude, JohnBultitude, John

Larkworthy, Leslie F.Larkworthy, Leslie F.

Povey, David C.Povey, David C.

Smith, Gallienus W.Smith, Gallienus W.

Dilworth, Jonathan R.Dilworth, Jonathan R.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9860002253

The complex has been prepared from or (thf = tetrahydrofuran) and the tertiary phosphine in toluene.In the crystal there are two independent trigonal-bipyramidal molecules with axial phosphine ligands.There is considerable distortion from regular co-ordination polyhedra and mean bond distances are V-Cl, 2.22 and 2.23 Angstroem, and V-P, 2.54 and 2.53 Angstroem.On long reflux of a solution of and PPh2Me in toluene, the complex is obtained.It contains six-co-ordinate vanadium(III) with meridional V-Cl bonds of average length 2.30 Angstroem.Other bond distances are V-N, 2.140(3) Angstroem and V-P, 2.56 Angstroem (av.).

View More

Products guided by the article

Product name:(acetonitrile)trichlorobis(methyldiphenylphosphine)vanadium(III)

Cas No:105451-08-9

105451-08-9

R&D Labs maybe for 105451-08-9

Relevant to this article

Hot Product