The Preparation and Crystal and Molecular Structures of Trichlorobis(methyldiphenylphosphine)vanadium(III) and its Acetonitrile Adduct

DOI: 10.1039/DT9860002253

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2253 - 2258 (1986)

Update date:2022-08-03

Topics:

Authors:

Bultitude, John

Larkworthy, Leslie F.

Povey, David C.

Smith, Gallienus W.

Dilworth, Jonathan R.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9860002253

The complex has been prepared from or (thf = tetrahydrofuran) and the tertiary phosphine in toluene.In the crystal there are two independent trigonal-bipyramidal molecules with axial phosphine ligands.There is considerable distortion from regular co-ordination polyhedra and mean bond distances are V-Cl, 2.22 and 2.23 Angstroem, and V-P, 2.54 and 2.53 Angstroem.On long reflux of a solution of and PPh2Me in toluene, the complex is obtained.It contains six-co-ordinate vanadium(III) with meridional V-Cl bonds of average length 2.30 Angstroem.Other bond distances are V-N, 2.140(3) Angstroem and V-P, 2.56 Angstroem (av.).

Full text of DOI:10.1039/DT9860002253

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:(acetonitrile)trichlorobis(methyldiphenylphosphine)vanadium(III)

Cas No:105451-08-9

R&D Labs maybe for 105451-08-9

Lian Xing Chemical Co.,Ltd.

Contact:0792-8228321

Address:10TH Floor No.121 binjiang Road Xunyang District
Pale Palm Imex

Contact:+36(21)2523420

Address:Head office: 1102 Budapest, SZENT LASZLO TER 24/B. 1/1., HUNGARY / CHINA
Second Pharma Co., Ltd

Contact:+86-575-82733999 0575-82732999

Address:hangzhou gulf fine chemical zone,shangyu city,zhejiang province
Guangxi Shanyun Biochemical Science and Technology Co., Ltd

Contact:+86-0772--6828887

Address:#2 Industrial Park of Luzhai County, Liuzhou, Guangxi, China
Hangzhou Ocean Chemical Co., Ltd.

website:http://www.hzoceanchem.com

Contact:+86-571-88025872, 28272092, 28272096

Address:Room 623 ,Building No 1 , COFCO Radius Commercial Center Xiwen Road, Xiacheng District, Hangzhou, Zhejiang Province, China

Relevant to this article

Conformational Aspects in the Design of Inhibitors for Serine Hydroxymethyltransferase (SHMT): Biphenyl, Aryl Sulfonamide, and Aryl Sulfone Motifs

Doi:10.1002/chem.201703244
(2017)
A general organocatalytic enantioselective malonate addition to α,β-unsaturated enones

Doi:10.1002/chem.200800673
(2008)
First total synthesis of the antifungal antibiotic thiobutacin

Doi:10.1016/j.tetlet.2008.06.036
(2008)
Diastereoselective Ni-catalyzed Negishi cross-coupling approach to saturated, fully oxygenated C-alkyl and C-aryl glycosides

Doi:10.1021/ja8041564
(2008)
THE HIGHLY STEREOSELECTIVE SYNTHESIS OF ALL-TRANS AND 13-CIS VITAMIN A VIA DOUBLE ELIMINATION REACTION

Doi:10.1246/cl.1985.1883
(1985)
Intramolecular C-H insertion reactions of (η⁵-Cyclopentadienyl)dicarbonyliron carbene complexes: Scope of the reactions and application to the synthesis of (±)-sterpurene and (±)-pentalenene

Doi:10.1021/jo001792i
(2001)

Article Doi