A NOVEL NUCLEOPHILIC SUBSTITUTION OF THE FORMYL GROUP IN p-NITROBENZALDEHYDE WITH SOME CARBANIONS

DOI: 10.1246/cl.1986.173

Source and publish data:

Chemistry Letters p. 173 - 176 (1986)

Update date:2022-08-05

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Authors:

Iwasaki, Genji

Saeki, Seitaro

Hamana, Masatomo

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Article abstract of DOI:10.1246/cl.1986.173

p-Nitrobenzaldehyde reacts with some active methylene compounds in the presence of a strong base at low temperatures to give p-substituted nitrobenzenes by the two-step course involving the initial formation of the aldol adducts and the subsequent displacement of the carbinol moieties with excess carbanions.

Full text of DOI:10.1246/cl.1986.173

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