
Journal of Organic Chemistry p. 592 - 598 (1987)
Update date:2022-08-04
Topics:
Hedstrand, David M.
Byrn, Stephen R.
McKenzie, Ann T.
Fuchs, Philip L.
An ABC ring intermediate for the synthesis of the quasinoidal antileukemia agent bruceantin has been prepared.Control of stereochemistry at C-8 was achieved by intramolecular conjugate addition of a nucleophile bound to the axial C-10 methyl group by a su
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