Ruthenium-catalyzed synthesis of vinyl carbamates from carbon dioxide, acetylene, and secondary amines

DOI: 10.1021/jo00378a039

Source and publish data:

Journal of Organic Chemistry p. 314 - 315 (1987)

Update date:2022-07-30

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Authors:

Sasaki, Yoshiyuki

Dixneuf, Pierre H.

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Article abstract of DOI:10.1021/jo00378a039

RuCl₃·3H₂O catalyzed the reaction of CO₂, acetylene, and secondary amines giving vinyl carbamates R₂NCO₂CH=CH₂ with a small amount of 2-butadienyl carbamates CH₂=C(R₂NCO₂)CH=CH₂.

Full text of DOI:10.1021/jo00378a039

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